Synthesis of silica-based porous monoliths with straight nanochannels using an ice-rod nanoarray as a template
- 3 July 2008
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of Materials Chemistry
- Vol. 18 (31), 3662-3670
- https://doi.org/10.1039/b806005c
Abstract
An attempt was made to synthesize a large-size silica porous monolith with straight and parallel nanochannels using an ice-rod nanoarray as a template. Since the previously reported ice templating methods allowed only the formation of micrometer-sized channels, special efforts were made to decrease the channel size down to the nanometer scale. Furthermore, such nanoporous silica monoliths were prepared not from an often-used and unstable hydrogel but from a stable colloidal silica solution. By increasing both the ice growing rate and the temperature gradient in the ice–water interface as much as possible, the channel size was reduced to 530 nm. Moreover, with the addition of the water-soluble polymers such as γ-cyclodextrin and dextran, the channel size was further decreased. Finally, using dextran polymer, the channel size reached as small as 180 nm, which is close to the theoretical lower limit (120 nm) in the present silica solution. This noticeable effect of the polymers may be explained from their strong interaction with water molecules through hydrogen bonding, but the most necessary condition for the polymers is that they never induce the aggregation of the silica particles in the solution. The methodology of obtaining much narrower channels using the ice templating method was discussed on the basis of the present results.Keywords
This publication has 39 references indexed in Scilit:
- Biocompatible MWCNT scaffolds for immobilization and proliferation of E. coliJournal of Materials Chemistry, 2007
- Morphology of resorcinol–formaldehyde gels obtained through ice-templatingCarbon, 2005
- Ordered Macroporous Silica by Ice TemplatingChemistry of Materials, 2005
- Formation of monolithic silica gel microhoneycombs (SMHs) using pseudosteady state growth of microstructural ice crystalsChemical Communications, 2004
- Preparation of resorcinol–formaldehyde carbon cryogel microhoneycombsCarbon, 2004
- Freeze gelation: a new option for the production of biological ceramic composites (biocers)Materials Letters, 2003
- Organic Templates for the Generation of Inorganic MaterialsAngewandte Chemie-International Edition, 2003
- Starch Gel Templating of Spongelike Macroporous Silicalite Monoliths and Mesoporous FilmsChemistry of Materials, 2002
- Template-based synthesis of nanomaterialsApplied Physics A, 2000
- Template‐directed nucleation and growth of inorganic materialsAdvanced Materials, 1994