We have observed that the supercurrent across phase-biased, highly transmitting atomic size contacts is strongly reduced within a broad phase interval around {\pi}. We attribute this effect to quasiparticle trapping in one of the discrete sub-gap Andreev bound states formed at the contact. Trapping occurs essentially when the Andreev energy is smaller than half the superconducting gap {\Delta}, a situation in which the lifetime of trapped quasiparticles is found to exceed 100 \mus. The origin of this sharp energy threshold is presently not understood.