A HNC study of asymmetrically charged hard spheres
- 15 December 1980
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 73 (12), 6272-6278
- https://doi.org/10.1063/1.440124
Abstract
The hypernetted chain equation (HNC) has been solved for two‐component highly asymmetric charged hard spheres and a systematic study of electrolytes ranging up to 20–1 has been carried out in the restricted primitive model. The cation–anion distribution function is found to exhibit complex structure for highly asymmetric electrolytes. Many component solutions of the HNC have been carried out. An application to a 1, 2, 3,‐1 electrolyte is discussed.Keywords
This publication has 23 references indexed in Scilit:
- Theory of simple classical fluids: Universality in the short-range structurePhysical Review A, 1979
- Integral equation approximations for dipolar fluidsMolecular Physics, 1979
- Microscopic Simulation of a Hydrogen PlasmaPhysical Review Letters, 1978
- Glass transition in the hard-sphere model. Relaxation effectsJournal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1978
- A variational approach to the theory of ionic solutionsThe Journal of Chemical Physics, 1976
- Charged hard spheres in a uniform neutralizing background using ‘mixed’ integral equationsMolecular Physics, 1976
- Glass transition in the hard-sphere modelJournal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1976
- Charge-asymmetric mixtures of electrolytes at low ionic strengthThe Journal of Physical Chemistry, 1974
- Optimized cluster expansions for classical fluids. IV. Primitive model electrolyte solutionsThe Journal of Chemical Physics, 1974
- Theory of mixed electrolyte solutions and application to a model for aqueous lithium chloride-cesium chlorideThe Journal of Physical Chemistry, 1970