Weakly charged polyelectrolyte gels : temperature and salt effects on the statics and the dynamics

Abstract
We measure the static structure factor S(q) and the cooperative diffusion coefficient Dc of weakly charged poly(acrylic acid) gels as a function of temperature and salt concentration. The variations of S(q) with these parameters agree semi-quantitatively with a recent model that predicts the occurrence of mesophases in similar systems. We use the theoretical S(q) to derive Dc in a simplified approach. The obtained expression describes satisfactorily the experimental behaviour of Dc