Mesoporous Ge/GeO2/Carbon Lithium-Ion Battery Anodes with High Capacity and High Reversibility
- 13 April 2015
- journal article
- research article
- Published by American Chemical Society (ACS) in ACS Nano
- Vol. 9 (5), 5299-5309
- https://doi.org/10.1021/acsnano.5b00817
Abstract
We report mesoporous composite materials (m-GeO2, m-GeO2/C, and m-Ge-GeO2/C) with large pore size which are synthesized by a simple block copolymer directed self-assembly. m-Ge/GeO2/C shows greatly enhanced Coulombic efficiency, high reversible capacity (1631 mA h g–1), and stable cycle life compared with the other mesoporous and bulk GeO2 electrodes. m-Ge/GeO2/C exhibits one of the highest areal capacities (1.65 mA h cm–2) among previously reported Ge- and GeO2-based anodes. The superior electrochemical performance in m-Ge/GeO2/C arises from the highly improved kinetics of conversion reaction due to the synergistic effects of the mesoporous structures and the conductive carbon and metallic Ge.Keywords
Funding Information
- National Research Foundation of Korea (2012R1A2A2A01002879, 2013R1A1A2074550)
- Ministry of Oceans and Fisheries
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