Analysis of the Atmosphere for Light Hydrocarbons

Abstract

A procedure has been developed for the analysis of trace quantities of light hydrocarbons in air. A freezetrap filled with chromatographic packing was installed in place of the gas sample loop of a flame ionization chromatograph. An air sample 0.1–0.5 liter volume was passed through the trap which was chilled with liquid oxygen. The trap wasthen brought to ice temperature and its contents simultaneously swept into the column. The resulting chrómatogram could be used to determine about 25 hydrocarbons through n-hexane. The minimum detectable concentration was below 1 ppb for these hydrocarbons. With such sensitivity it is possible to make useful measurements even on samples of light air pollution. Air samples from the Riverside area were analyzed in this fashion starting in the summer of 1965. The relative amounts of these hydrocarbons were then compared with the distribution reported for the various known hydrocarbon sources. The attenuation of the more reactive hydrocarbons by photolysis was also observed. A system for irradiating trapped air samples was also constructed. Samples were collected in 5-gallon borosilicate bottles which were then irradiated with ultraviolet radiation and the concentration changes followed.