The crystal structure of [Mn(salpn)(acetate)]2(H2O)3; the first example of a manganese(III) Schiff base polymeric complex containing a dimeric repeat unit [salpn =N,N′-bis(salicylidene)-1,3-diaminopropane]
- 1 January 1992
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 1524-1526
- https://doi.org/10.1039/c39920001524
Abstract
The crystal structure of [Mn(salpn)(OAc)]2(H2O)3 shows it to be a polymeric array, with the Mn(salpn) units bridged by acetate groups in an anti–anti configuration, with three hydrogen-bonded water molecules per monomer; the two ligands per monomer are rotated 180° with respect to each other.Keywords
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