Tetrathiafulvalene–FePS3layered intercalation compound: a new type of organic–inorganic metal

Abstract
Layered FePS3 preintercalated with tetraethylammonium cations reacts with (TTF)3(BF4)2 in acetonitrile to yield Fe1 –xPS3(TTF)2x(x≈ 0.18). This intercalation compound has a metallic character, in contrast to pure FePS3 which is a semiconductor.

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