Spin-Canting and Metamagnetic Behavior in a New Species from the Hydrothermal Co(II)-trans-3-Pyridylacrylate System
- 31 August 2009
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 48 (19), 9205-9213
- https://doi.org/10.1021/ic900886y
Abstract
Hydrothermal reaction of CoCl2 with trans-3-pyridylacrylic acid (3-pycaH) and Et3N results in the formation of a new three-dimensional network formulated as [{Co4(μ-H2O)2(3-pyca)8}0.94{Co5(μ3-OH)2(3-pyca)8}0.06]. Magnetic measurements reveal that spin-canting and metamagnetic behavior coexist in this compound with a critical temperature at 9.5 K.Keywords
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