Clarification of the predominant emission sources of antimony in airborne particulate matter and estimation of their effects on the atmosphere in Japan
- 1 January 2009
- journal article
- Published by CSIRO Publishing in Environmental Chemistry
- Vol. 6 (2), 122-132
- https://doi.org/10.1071/en08107
Abstract
Environmental context. The remarkable enrichment of potentially toxic antimony (Sb) in inhalable airborne particulate matter has become of great environmental concern among recent air pollution issues. The present study clarifies the predominant sources of Sb by focusing on the similarities in elemental composition, particle size distributions, and microscopic images found in ambient airborne particles and several potential sources. We identify automotive brake abrasion dust and fly ash emitted from waste incineration as dominant sources of atmospheric Sb in Japan. These results will contribute towards an in-depth understanding of the cycles and fates of Sb in the environment. By focusing on the similarities in elemental composition, particle size distributions of elemental concentrations, and microscopic images between ambient airborne particulate matter (APM) and several potential sources, we discuss the predominant sources of antimony (Sb) in APM in Japan. The distribution of Sb concentration in size-classified ambient APM showed a characteristic bimodal profile in which peaks were found in coarse (3.6–5.2 μm) and fine (0.5–0.7 μm) fractions. Elemental ratios, particle sizes, and microscopic images observed in the coarse APM fractions were found to be in good agreement with those of brake abrasion dust. However, in the fine APM fractions, fly ash originating from waste incineration was identified as the most probable source of Sb. Chemical mass balance analysis was performed to determine the effects of the emission sources of Sb, and it was revealed that brake abrasion dust and waste fly ash were the dominant sources of Sb in the coarser and the finer fractions of APM, respectively. The present study provides important clues to understanding the cycles and fates of Sb in the environment.Keywords
This publication has 25 references indexed in Scilit:
- Atmospheric Sb in the Arctic during the past 16,000 years: Responses to climate change and human impactsGlobal Biogeochemical Cycles, 2008
- Mercury cycling in the Arctic - does enhanced deposition flux mean net-input?Environmental Chemistry, 2008
- Characteristics of trace elements and lead isotope ratios in PM2.5 from four sites in ShanghaiJournal of Hazardous Materials, 2007
- Cadmium—A Priority PollutantEnvironmental Chemistry, 2006
- A comparison of antimony and lead profiles over the past 2500 years in Flanders Moss ombrotrophic peat bog, ScotlandJournal of Environmental Monitoring, 2005
- Lithogenic, oceanic and anthropogenic sources of atmospheric Sb to a maritime blanket bog, Myrarnar, Faroe IslandsJournal of Environmental Monitoring, 2005
- Increasing atmospheric antimony contamination in the northern hemisphere: snow and ice evidence from Devon Island, Arctic CanadaJournal of Environmental Monitoring, 2005
- Foreword: Research Front—Arsenic BiogeochemistryEnvironmental Chemistry, 2005
- Antimony in recent, ombrotrophic peat from Switzerland and Scotland: Comparison with natural background values (5,320 to 8,020 14C yr BP) and implications for the global atmospheric Sb cycleGlobal Biogeochemical Cycles, 2004
- Characteristics of lead isotope ratios and elemental concentrations in PM10 fraction of airborne particulate matter in Shanghai after the phase-out of leaded gasolineAtmospheric Environment, 2004