X-ray reflectivity measurements of the expansion of carbon films upon annealing

Abstract
Measurements have been made of the x-ray reflectivity from ultrathin, amorphous carbon films both before and after annealing. Analysis of the x-ray results indicates that annealing causes an increase in film thickness with a corresponding decrease in density. Such behavior is uncharacteristic of amorphous thin films and is interpreted as being due to changes in the interatomic bonding associated with transition to a more graphitic microstructure.