Sintering of Nano-Particle Powders: Simulations and Experiments
- 1 November 1996
- journal article
- research article
- Published by Informa UK Limited in Materials and Manufacturing Processes
- Vol. 11 (6), 905-923
- https://doi.org/10.1080/10426919608947541
Abstract
The sintering and consolidation of nano-particle powders were investigated using both computer simulation and direct experimentation. Molecular dynamics was employed to investigate the sintering of Cu nano-particles. Both spherical and cylindrical particles were employed in these simulations. The work demonstrates that sintering of these systems can take place on a time scale of tens of picoseconds, owing to the high shear stresses that develop at small particle contacts. For two and three particle sintering, it was observed that mass transport occurs by plastic flow. It was also found that crystallographically misaligned particles rotate to form low energy boundaries. The influence of the initial packing configuration was also investigated. Full densification occurs during pressureless sintering at room temperature only if the nano-particle assembly is close-packed. The effect of both isostauc and uniaxial stress on densification of Cu was also studied. Grain boundary sliding and grain boundary relaxation were also investigated. Experimental measurements of densification of bulk specimens undergoing shear deformation provide information on the macroscopic sintering behavior of large assemblies of nano-crystals. The constitutive law for densification of nano-crystalline TiO2 has been obtained. Attempts are made to relate the observed macroscopic sintering behavior of this system to the microscopic processes elucidated by the simulations.Keywords
This publication has 16 references indexed in Scilit:
- The sintering of two particles by surface and grain boundary diffusion—a two-dimensional numerical studyActa Metallurgica et Materialia, 1995
- Molecular-dynamics method for simulating heterogeneous condensed matter at constant pressurePhysical Review B, 1995
- A computer simulation method for sintering in three-dimensional powder compactsJournal of Materials Science, 1994
- Radiation-induced amorphization of ordered intermetallic compounds CuTi, , and : A molecular-dynamics studyPhysical Review B, 1991
- Thermodynamics of Densification: I, Sintering of Simple Particle Arrays, Equilibrium Configurations, Pore Stability, and ShrinkageJournal of the American Ceramic Society, 1989
- Powder Processing Science and Technology for Increased ReliabilityJournal of the American Ceramic Society, 1989
- Nanocrystalline materialsProgress in Materials Science, 1989
- Dispersoid growth in Ni-2ThO2 due to self-diffusion sintering of particle clustersMetallurgical Transactions, 1974
- A first report on sintering diagramsActa Metallurgica, 1974
- Coalescence of Two Spheres by Surface DiffusionJournal of Applied Physics, 1966