Number of outer electrons as descriptor for adsorption processes on transition metals and their oxides
- 2 January 2013
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Science
- Vol. 4 (3), 1245-1249
- https://doi.org/10.1039/c2sc21601a
Abstract
The trends in adsorption energies of the intermediates of the oxygen reduction and evolution reactions on transition metals and their oxides are smoothly captured by the number of outer electrons. This unique descriptor permits the construction of predictive adsorption-energy grids and explains the existence of scaling relationships among these compounds.Keywords
This publication has 37 references indexed in Scilit:
- A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital PrinciplesScience, 2011
- Design principles for oxygen-reduction activity on perovskite oxide catalysts for fuel cells and metal–air batteriesNature Chemistry, 2011
- Universality in Oxygen Evolution Electrocatalysis on Oxide SurfacesChemCatChem, 2011
- Trends in Stability of Perovskite OxidesAngewandte Chemie-International Edition, 2010
- Volcano Relation for the Deacon Process over Transition‐Metal OxidesChemCatChem, 2010
- Solid oxide fuel cells (SOFCs): a review of an environmentally clean and efficient source of energyRenewable and Sustainable Energy Reviews, 2002
- Structure and Reactivity of Perovskite-Type OxidesAdvances in Catalysis, 1989
- Electrocatalytic properties of transition metal oxides for oxygen evolution reactionMaterials Chemistry and Physics, 1986
- Electrocatalysis in the anodic evolution of oxygen and chlorineElectrochimica Acta, 1984
- The Electrocatalysis of Oxygen Evolution on PerovskitesJournal of the Electrochemical Society, 1984