Recommended Liquid–Liquid Equilibrium Data. Part 4. 1-Alkanol–Water Systems

Abstract

The recommended liquid–liquid equilibrium (LLE) data for 19 binary 1-alkanol–water systems have been obtained after critical evaluation of all data (527 data sets) reported in the open literature up to the end of 2004. An equation for prediction of the 1-alkanol solubility was developed. The predicted 1-alkanol solubility was used for calculation of water solubility in the second liquid phase. The LLE calculations were done with the equation of state appended with a chemical term proposed by Góral. The recommended data were presented in the form of individual pages containing tables and all the references.