A water-compatible, highly active and reusable PEG-coated mesoporous silica-supported palladium complex and its application in Suzuki coupling reactions
- 4 May 2006
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 23,p. 2495-2497
- https://doi.org/10.1039/b605733k
Abstract
A highly active heterogeneous palladium catalyst was prepared from coated mesoporous materials which contain a layer of readily available PEG with a labile coordinating ability for palladium. The aqueous suspension of the catalyst may be reused several times by simple extraction of the aqueous reaction mixture with ether to remove the product.Keywords
This publication has 32 references indexed in Scilit:
- Suzuki-Miyaura Cross-Coupling of Aryl Chlorides in Water Using Ligandless Palladium on Activated CarbonSynlett, 2005
- Modular Diamino‐ and Dioxophosphine Oxides and Chlorides as Ligands for Transition‐Metal‐Catalyzed C-C and C-N Couplings with Aryl ChloridesAngewandte Chemie-International Edition, 2005
- Catalytic performance and elution of Pd in the Heck reaction over zeolite-supported Pd cluster catalystJournal of Catalysis, 2005
- Catalysts for Suzuki−Miyaura Coupling Processes: Scope and Studies of the Effect of Ligand StructureJournal of the American Chemical Society, 2005
- Comparison of mesoporous silica and alumina supports for palladium-catalyzed carbon–carbon coupling reactions: unexpected high acceleration by supported cetyltrimethylammonium bromideMicroporous and Mesoporous Materials, 2001
- Superior performance of a chiral catalyst confined within mesoporous silicaChemical Communications, 1999
- Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom PoresScience, 1998
- Palladium-Catalyzed Cross-Coupling Reactions of Organoboron CompoundsChemical Reviews, 1995
- Fine Feathers Make Fine Birds: The Heck Reaction in Modern GarbAngewandte Chemie-International Edition, 1995
- Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanismNature, 1992