Cross-Linked Perylene Diimide-Based n-Type Interfacial Layer for Inverted Organic Photovoltaic Devices
- 7 November 2011
- journal article
- Published by American Chemical Society (ACS) in ACS Applied Materials & Interfaces
- Vol. 3 (11), 4381-4387
- https://doi.org/10.1021/am201027j
Abstract
This contribution describes the synthesis and characterization of a perylene diimide (PDI)-based n-type semiconductor and its application to organic photovoltaic (OPV) devices having inverted architecture. Films of N,N′-bis(3-trimethoxysilylpropyl)-1,6,7,12-tetrachloroperylene-3,4,9,10-tetracarboxyldiimide (Cl4PSi2) and blends of this material with various polymers are solution-deposited on tin-doped indium oxide (ITO) substrates as interfacial layers (IFLs). The organic IFL described in this work is based on the air- and light-stable PDI core, annealed at low temperatures compatible with flexible substrates, and crosslinks in air for compatibility with device fabrication. Morphological, optical, and electrochemical analysis of these IFL films demonstrate predominantly smooth surfaces and HOMO and LUMO energies of ∼4.5 and 7.0 eV, respectively, which are ideal for accepting electrons and blocking holes in inverted devices. A cationic silane species is added to the Cl4PSi2 at an optimum ∼2–5 wt % to reduce IFL series resistance and enhance device performance. Also, a short light soaking procedure is necessary for completed devices to achieve high fill factors in current density–voltage analysis, a phenomenon previously only observed for inverted devices having an n-type inorganic IFL.Keywords
This publication has 53 references indexed in Scilit:
- π-Conjugated Polymers for Organic Electronics and Photovoltaic Cell ApplicationsChemistry of Materials, 2010
- Small Molecule Solution-Processed Bulk Heterojunction Solar CellsChemistry of Materials, 2010
- Polymer–fullerene bulk heterojunction solar cellsReports on Progress in Physics, 2010
- A New Class of Semiconducting Polymers for Bulk Heterojunction Solar Cells with Exceptionally High PerformanceAccounts of Chemical Research, 2010
- Polyphenylene-Based Materials for Organic PhotovoltaicsChemical Reviews, 2010
- Molecular Semiconductors in Organic Photovoltaic CellsChemical Reviews, 2010
- Charge Photogeneration in Organic Solar CellsChemical Reviews, 2010
- Organic/Organic′ Heterojunctions: Organic Light Emitting Diodes and Organic Photovoltaic DevicesMacromolecular Rapid Communications, 2009
- Polymer‐Fullerene Bulk‐Heterojunction Solar CellsAdvanced Materials, 2009
- Organic photovoltaicsEnergy & Environmental Science, 2009