Abstract
The polarization of sodium D line resonance radiation excited by plane polarized light in a magnetic field parallel to the electric vector of the exciting light increases from 16.5 percent in zero field to almost 50 percent in a field of 300 gauss as a consequence of the Paschen-Back effect of the hyperfine structure. The experimental results are well fitted by a curve calculated with A(3P322)=7.45×104 cm1 and τ(3P322)=1.64×108 sec. These results are for a nuclear moment of 32(h2π) which was at first thought to give too low zero field polarization (15.27 percent). The higher polarization is the effect of proximity of hyperfine levels in 3P322.

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