CORRELATIONS OF ETHYLENIC PROTON COUPLING CONSTANTS WITH ELECTRONEGATIVITY
- 1 January 1962
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 40 (1), 1-4
- https://doi.org/10.1139/v62-001
Abstract
A strong correlation is found between the electronegativity, Ex, and the three proton coupling constant of the vinyl group in over a hundred compounds of the type CH2 = CHX. This correlation extends over the range Ex = 4 to 1 and over the range Jgem + Jcis + Jtrans = 14 to 50 c.p.s. Simple implications and some useful applications of this correlation are discussed.Keywords
This publication has 3 references indexed in Scilit:
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- Angular Dependence of Electron-Coupled Proton Interactions in CH2 GroupsThe Journal of Chemical Physics, 1959
- Orientation Effects in Bimolecular Ionic ReactionsThe Journal of Chemical Physics, 1935