The Correct Application of the Gibbs-Helmholtz Equation to Reversible Galvanic Cells in Which the Compositions of Some of the Phases Vary with Temperature
- 1 October 1953
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 21 (10), 1827-1828
- https://doi.org/10.1063/1.1698671
Abstract
The detailed proof is given that the Gibbs‐Helmholtz equation dΔFcell/dT=—ΔScell is directly applicable to any reversible galvanic cell, regardless of how the compositions of any phases present may vary with the temperature.Keywords
This publication has 2 references indexed in Scilit:
- Concerning the Temperature Coefficient of the emf of Reversible Galvanic Cells Operated at Variable ConcentrationThe Journal of Chemical Physics, 1951
- The Correct Application of the Gibbs—Helmholtz Equation to Reversible Galvanic Cells in which Several Phases Are in Equilibrium at One of the ElectrodesJournal of the American Chemical Society, 1950