A high-performance selective oxidation system for the facile production of fine chemicals
- 19 April 2007
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 19,p. 1924-1926
- https://doi.org/10.1039/b618090f
Abstract
MnIIIAlPO-5 and CrVIAlPO-5 redox (microporous) catalysts are effective, in the presence of dissolved acetylperoxyborate (APB) under mild conditions (333–373 K), and much superior to the titanosilicate, TS-1 (also a single-site heterogeneous catalyst), in the selective oxidation of primary, secondary, benzylic and other unsaturated alcohols, p-cymene, methyl cyclohexene and other speciality organics which are of value in the fine-chemical and pharmaceutical industries.Keywords
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