Extended-x-ray-absorption-fine-structure study of small Fe molecules isolated in solid neon

Abstract

We have used rare gas matrix isolation techniques in combination with extended x-ray absorption fine structure (EXAFS) to study the variation in interatomic distances for small Fe molecules in solid neon. A considerable contraction in the interatomic distances was observed for the metal molecules. An Fe-Fe distance of 2.02 ± 0.02 Å for the lowest concentration of metal was observed. This is in good agreement with early EXAFS measurements in ${\mathrm{Fe}}_2$-Ar. We also carried out a careful study of the x-ray-absorption near-edge structure (XANES), and observed the appearance of considerable structure for a 1.5-at.% Fe sample. The XANES spectra were analyzed in terms of $1s$-to-($3d,4s$) and $1s$-to-$4p$ transitions.