Effects of Constant Voltage on Time Evolution of Propagating Concentration Polarization
- 29 March 2010
- journal article
- letter
- Published by American Chemical Society (ACS) in Analytical Chemistry
- Vol. 82 (8), 3114-3117
- https://doi.org/10.1021/ac100432q
Abstract
We extend the analytical theory of propagating concentration polarization (CP) to describe and compare the effects of constant-voltage versus constant-current conditions on the transient development of CP enrichment and depletion zones. We support our analysis with computational and experimental results. We find that at constant voltage, enrichment and depletion regions spread as t1/2 as opposed to the previously observed t1 scaling for constant current conditions. At low, constant voltages, the growth and propagation of CP zones can easily be misinterpreted as nonpropagating behavior.Keywords
This publication has 14 references indexed in Scilit:
- Theory and experiments of concentration polarization and ion focusing at microchannel and nanochannel interfacesChemical Society Reviews, 2010
- Stabilization of Ion Concentration Polarization Using a Heterogeneous Nanoporous JunctionNano Letters, 2009
- Electropreconcentration with Charge-Selective NanochannelsAnalytical Chemistry, 2008
- The influence of membrane ion-permselectivity on electrokinetic concentration enrichment in membrane-based preconcentration unitsLab on a Chip, 2008
- Non-equilibrium electrokinetic micro/nano fluidic mixerLab on a Chip, 2008
- Transient Effects on Microchannel Electrokinetic Filtering with an Ion-Permselective MembraneAnalytical Chemistry, 2008
- Pre-binding dynamic range and sensitivity enhancement for immuno-sensors using nanofluidic preconcentratorLab on a Chip, 2008
- Electrokinetic Protein Preconcentration Using a Simple Glass/Poly(dimethylsiloxane) Microfluidic ChipAnalytical Chemistry, 2006
- Million-fold Preconcentration of Proteins and Peptides by Nanofluidic FilterAnalytical Chemistry, 2005
- Ion-Enrichment and Ion-Depletion Effect of Nanochannel StructuresNano Letters, 2004