Radical Addition to “Cation Pool”. Reverse Process of Radical Cation Fragmentation
- 3 May 2005
- journal article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 127 (20), 7324-7325
- https://doi.org/10.1021/ja0511218
Abstract
The reaction of an N-acyliminium ion with an alkyl iodide and hexabutyldistannane took place to give the alkylation product. A mechanism involving the addition of an alkyl radical to an N-acyliminium ion to produce the corresponding radical cation has been suggested.Keywords
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