Lyotropic nematics : molecular aggregation and susceptibilities

Abstract
Alterations of the concentrations of certain components in a lyotropic nematic mesophase may change the sign of the anisotropy of its magnetic susceptibility, Δχ. We report here : 1) the determination of the sign of Δχ by optical observation of the textures in the presence of a magnetic field, 2) the results of an X-ray diffraction study of the aggregation of the amphiphilic molecules. We conclude that the inversion of Δχ results from the different shapes of the aggregates