Reactive scattering of O(1D)+HD: Product speed and angle distributions
- 22 September 1995
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 103 (12), 5164-5167
- https://doi.org/10.1063/1.470606
Abstract
The reaction dynamics of O(1D)+HD → OH+D and OD+H was investigated at a collision energy of 4.55 kcal/mole in a crossed‐beam apparatus. The speed and angle distributions of H(D) products were interrogated using Doppler‐shift measurements in a (1+1) REMPI (resonantly enhanced multiphoton ionization) detection scheme. Both product channels exhibited marked forward–backward asymmetry in the angular distributions and the translational energy release to the OD+H channel was substantially larger, about 1.4 on the average, than that to the OH+D product.Keywords
This publication has 27 references indexed in Scilit:
- Reaction dynamics of vibrationally excited H2Chemical Physics, 1993
- The influence of vibrational and translational motion on the reaction dynamics of O(1D)+H2(1Σ+g,v)The Journal of Chemical Physics, 1992
- Product energy distribution of hydroxyl radicals in O(1D2) + HCl → OH + ClChemical Physics Letters, 1989
- On the dynamics of abstraction, insertion, and addition-elimination reactions in the gas phaseThe Journal of Physical Chemistry, 1988
- The nascent product vibrational energy distribution of the reaction O(1D) + H2 by the grating selection chemical laser techniqueChemical Physics Letters, 1986
- Reaction dynamics of O(1D2)+H2, HD, D2: OH, OD(X 2Πi) product internal energy distributionsThe Journal of Chemical Physics, 1986
- Isotopic branching ratio for the reaction A+HD→AD(H)+H(D)The Journal of Chemical Physics, 1985
- Vibrational excitation of OH(X2Π) produced in the reaction of O(1D) with H2Chemical Physics Letters, 1983
- Reactive scattering of O(1D) + H2Chemical Physics Letters, 1981
- Chemical dynamics of the reactions of O(1D2) with saturated hydrocarbonsThe Journal of Chemical Physics, 1980