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Dearomatising cyclisations of lithiated N-benzylbenzamides
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Dearomatising cyclisations of lithiated N-benzylbenzamides
Dearomatising cyclisations of lithiated N-benzylbenzamides
AA
Anjum Ahmed
Anjum Ahmed
Jonathan Clayden
Jonathan Clayden
SY
Samreen A. Yasin
Samreen A. Yasin
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1 January 1999
journal article
research article
Published by
Royal Society of Chemistry (RSC)
in
Chemical Communications
No. 3
,
p.
231-232
https://doi.org/10.1039/a808218i
Abstract
On treatment with Bu
t
Li in the presence of HMPA,
N
-benzylbenzamides undergo anionic cyclisation with dearomatisation to give an extended amide enolate which reacts with electrophiles to yield bicyclic cyclohexadiene derivatives.
Keywords
TREATMENT
LITHIATED
CYCLISATIONS
BENZYLBENZAMIDES
HMPA
REACTS
GIVE
BUTLI
BICYCLIC
ANIONIC
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Cited by 48 articles