Temperature dependence in the multiphoton dissociation of 32SF6
- 15 June 1979
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 70 (12), 5672-5675
- https://doi.org/10.1063/1.437443
Abstract
The multiphoton dissociation of 32SF6 at 10.59 μm has been studied as a function of the temperature between 223 and 413 K. The observed decrease of the reaction yield with increasing temperature varies strongly with the laser energy fluence at the applied conditions. Rate constants for the unimolecular decomposition of sulfur hexafluoride induced by the monochromatic infrared radiation are derived at 223, 293, and 343 K.Keywords
This publication has 17 references indexed in Scilit:
- Theory of unimolecular reactions induced by monochromatic infrared radiationThe Journal of Chemical Physics, 1978
- The selective dissociation of SF6 in an intense ir field: A molecular beam study on the influence of laser wavelength and energyThe Journal of Chemical Physics, 1978
- Infrared-laser-induced unimolecular reactionsPhysics Today, 1978
- Multiple-photon isotope separation in SF6: Effect of laser pulse shape and energy, pressure, and irradiation geometryThe Journal of Chemical Physics, 1977
- Collisionless dissociation of SF6 using two resonant frequency CO2 laser fieldsOptics Communications, 1977
- Collisionless Multiphoton Dissociation of S: A Statistical Thermodynamic ProcessPhysical Review Letters, 1977
- Absorption of CO2 laser pulses at different wavelengths by ground-state and vibrationally heated SF6Optics Communications, 1977
- Energy and pressure dependence of the CO2 laser induced dissociation of sulfur hexafluorideApplied Physics A, 1977
- Collisionless dissociation and isotopic enrichment of SF6 using high-powered CO2 laser radiationOptics Communications, 1977
- Sulfur isotope enrichment in SF6 by high intensity CO2 laser radiationOptics Communications, 1976