Ligand-Free Palladium Catalysis of the Suzuki Reaction in Water Using Microwave Heating
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- 30 July 2002
- journal article
- letter
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 4 (17), 2973-2976
- https://doi.org/10.1021/ol0263907
Abstract
We report the ligand-free palladium catalysis of the Suzuki reaction in water using microwave heating. Our methodology uses low palladium loadings (0.4 mol %), is fast (5−10 min reaction time), and is useful for couplings involving boronic acids and aryl iodides, bromides, and chlorides.Keywords
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