[PtMe(iPr3P)2]+: a Pt(ii) complex with an agostic interaction that undergoes C–H activation
- 1 January 2004
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 21,p. 2398-2399
- https://doi.org/10.1039/b410846a
Abstract
The T-shaped Pt(II) complex [PtMe(iPr3P)2][1-H-closo-CB11Me11], which is stabilised by an agostic interaction, undergoes acid-catalysed intramolecular C–H activation in the presence of THF to afford cyclometallated [Pt(THF)(iPr3P)(iPr2PCHMeCH2)][1-H-closo-CB11Me11].Keywords
This publication has 16 references indexed in Scilit:
- HOMOGENEOUS HYDROCARBON CH BOND ACTIVATION AND FUNCTIONALIZATION WITH PLATINUMAdvances in Inorganic Chemistry, 2003
- C−H Bond Activation by Cationic Platinum(II) Complexes: Ligand Electronic and Steric EffectsJournal of the American Chemical Society, 2002
- A Neutral Three-Coordinate Alkylrhodium(I) Complex: Stabilization of a 14-Electron Species by γ-C−H Agostic Interactions with a Saturated Hydrocarbon GroupAngewandte Chemie International Edition, 2001
- Crystal Structure of n-Bu3Sn+ CB11Me12-Journal of the American Chemical Society, 2000
- Synthetic, Structural, and Solution Thermochemical Studies in the Dimethylbis(phosphine)platinum(II) System. Dichotomy between Structural and Thermodynamic TrendsOrganometallics, 1999
- Redox Chemistry of Dimethylplatinum(II) Diimine Complexes. Oxidatively Induced Pt−Me Transfer between Transient Platinum(III) Cation RadicalsOrganometallics, 1998
- Ligand Metalation in Triisopropylphosphine−Platinum(II) CompoundsOrganometallics, 1998
- Syntheses and Structures of Alkyl and Aryl Halide Complexes of the Type [(PiPr3)2PtH(η1-XR)]BArf and Analogues with Et2O, THF, and H2 Ligands. Halide-to-Metal π Bonding in Halocarbon ComplexesJournal of the American Chemical Society, 1996
- Platinum ethyl complexes with β-agostic Pt–H–C bondingJ. Chem. Soc., Dalton Trans., 1992
- Co-ordinatively unsaturated diphosphine platinum(II) alkyl cations: a new class of β-agostic complexesJournal of the Chemical Society, Chemical Communications, 1988