Highly Stable Water Splitting on Oxynitride TaON Photoanode System under Visible Light Irradiation

Abstract

Highly stable photoelectrochemical water splitting is demonstrated for the first time on a tantalum oxynitride (TaON) photoanode under visible light irradiation. Highly dispersed CoO_x nanoparticles on the TaON photoanode efficiently scavenge photogenerated holes and effectively suppress self-oxidative deactivation of the TaON surface, resulting in a stable photocurrent. The use of highly dispersed CoO_x cocatalyst on TaON together with phosphate solutions significantly increased the photocurrent due to the formation of a cobalt/phosphate phase. This enabled us to stably split water into H₂ and O₂ under visible light irradiation at a relatively low applied bias (0.6 V vs Pt counter electrode).