Distance dependence in photoinduced intramolecular electron transfer. Additional remarks and calculations
- 1 December 1987
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 87 (11), 6623-6625
- https://doi.org/10.1063/1.453447
Abstract
Rate constants for photoinduced intramolecular electron transfer are calculated for four of the molecules studied by Hush et al. The electronic factor is obtained in quantum chemical calculations using the CNDO/S method. The results agree reasonably well with experiments for the forward reaction. Possible reasons for the disagreement for the charge recombination process are offered.Keywords
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