Rates of Addition of Methyl Radicals to Olefins in the Gas Phase
- 1 March 1967
- journal article
- conference paper
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 46 (5), 1694-1702
- https://doi.org/10.1063/1.1840923
Abstract
A technique has been developed and used to measure relative rates of reaction of methyl radicals with a number of olefins in the gas phase at 80°, 130°, and 180°C. The rate constants, activation energies, and pre-exponential factors have been determined.Keywords
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