The Thermodynamics of Reversible Galvanic Cells in Which the Compositions of Some of the Phases Vary with Temperature
- 1 October 1953
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 21 (10), 1829-1830
- https://doi.org/10.1063/1.1698672
Abstract
The entropy change calculated from the temperature coefficient of electromotive force of a reversible galvanic cell, in which the compositions of some of the phases vary with temperature, corresponds to a unique correct chemical reaction. The equivalence of methods suggested by Barieau and by Li for determining this correct reaction is shown. The method of Barieau is simpler and more direct and presents the results in a more convenient form.Keywords
This publication has 3 references indexed in Scilit:
- The Correct Application of the Gibbs-Helmholtz Equation to Reversible Galvanic Cells in Which the Compositions of Some of the Phases Vary with TemperatureThe Journal of Chemical Physics, 1953
- Concerning the Temperature Coefficient of the emf of Reversible Galvanic Cells Operated at Variable ConcentrationThe Journal of Chemical Physics, 1951
- The Correct Application of the Gibbs—Helmholtz Equation to Reversible Galvanic Cells in which Several Phases Are in Equilibrium at One of the ElectrodesJournal of the American Chemical Society, 1950