Tavorite Lithium Iron Fluorophosphate Cathode Materials: Phase Transition and Electrochemistry of LiFePO[sub 4]F–Li[sub 2]FePO[sub 4]F
- 1 January 2010
- journal article
- Published by The Electrochemical Society in Electrochemical and Solid-State Letters
- Vol. 13 (4), A43-A47
- https://doi.org/10.1149/1.3298353
Abstract
We have synthesized by a simple solid-state route as a pure single phase, which we show is isostructural with that of the minerals tavorite and amblygonite, and we report the first isolation of its fully lithium-inserted crystalline analog, . We show that the latter adopts a triclinic tavorite-type framework that is very closely related to the parent phase. The redox activity between these two compositions is very facile and occurs with an 8% change in volume to result in a reversible and stable capacity of about 145 mAh/g. The electrochemical cycling at both room temperature and is very stable.Keywords
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