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A method for olefin inversion via phosphine oxides
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A method for olefin inversion via phosphine oxides
A method for olefin inversion via phosphine oxides
AB
Alexander J. Bridges
Alexander J. Bridges
GW
Gordon H. Whitham
Gordon H. Whitham
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1 January 1974
journal article
Published by
Royal Society of Chemistry (RSC)
in
Journal of the Chemical Society, Chemical Communications
No. 4
,
p.
142-143
https://doi.org/10.1039/c39740000142
Abstract
Treatment of epoxides with Ph
2
PLi–THF followed by H
2
O
2
–AcOH gives, by a single inversion,
β
-hydroxy-diphenylphosphine oxides; the latter can be fragmented stereospecifically to olefins on treatment with an appropriate base.
Keywords
TREATMENT
OLEFIN
PH2PLI
DIPHENYLPHOSPHINE
STEREOSPECIFICALLY
ACOH
EPOXIDES
HYDROXY
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Cited by 32 articles