Manganese and Magnesium Homochiral Materials: Decoration of Honeycomb Channels with Homochiral Chains
- 30 October 2007
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 129 (46), 14168-14169
- https://doi.org/10.1021/ja076532y
Abstract
Five homochiral open-framework materials based on manganese and magnesium camphorates exhibit homochiral connectivity from one- to three-dimensions, highlighting the versatility of the synthetic system reported here. Two compounds contain a column of homochiral chains lining up the honeycomb channels of 3-D metal−oxygen frameworks, an unusual feature previously unobserved in inorganic−organic hybrids.Keywords
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