Ionization of Strong Electrolytes. X. Proton Magnetic Resonance of the Ternary System HClO4-DClO4-H2O-D2O
- 1 March 1968
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 48 (5), 2275-2284
- https://doi.org/10.1063/1.1669425
Abstract
New measurements of the nuclear magnetic resonance(NMR) of perchloric acidsolutions furnish results of higher accuracy (about 0.002 ppm in the chemical shift) between 0° and 65°C. Discrepancies in the degrees of dissociation derived from older NMR data and Raman intensities are ascribed to short‐comings in the earlier interpretation. Extension of the measurements to deuterium solutions furnishes information to be used in the discussion of the molecular state of the acid and of the hydrogen ion.Keywords
This publication has 21 references indexed in Scilit:
- Ionization of Strong Electrolytes. IX. Proton Magnetic Resonance in the Ternary System HNO3—DNO3—H2O—D2OThe Journal of Chemical Physics, 1967
- On the Thermodynamics of Solutions. VII. Critical Properties of MixturesThe Journal of Chemical Physics, 1962
- Nuclear Magnetic Resonance Effects in Aqueous Solutions of 1–1 ElectrolytesThe Journal of Chemical Physics, 1962
- A new procedure for preparation of anhydrous perchloric acid employing anhydrous magnesium perchlorateTalanta, 1961
- A chemical hydration treatment of concentrated acid solutionsDiscussions of the Faraday Society, 1957
- Ionization of Strong Electrolytes. III. Proton Magnetic Resonance in Nitric, Perchloric, and Hydrochloric AcidsThe Journal of Chemical Physics, 1954
- The Preparation of Anhydrous Perchloric AcidJournal of the American Chemical Society, 1953
- cis—trans Isomerization and cis-Peak Effect in the α-Carotene Set and in Some Other Stereoisomeric SetsJournal of the American Chemical Society, 1944
- The Ionization of Strong Electrolytes. I. General Remarks, Nitric AcidJournal of the American Chemical Society, 1943
- The Heats of Ionization of Water, Ammonium Hydroxide, Carbonic, Phosphoric, and Sulfuric Acids. The Variation of Ionization Constants with Temperature and the Entropy Change with IonizationJournal of the American Chemical Society, 1937