Effect of non-muffin-tin terms on the electronic structure of transition metals: Niobium

Abstract
The effect of removing the muffin-tin approximation in a relativistic-augmented-plane-wave calculation of the electronic structure of Nb is described. The most significant effect found is that two experimentally observed orbits occur in a fully non-muffin-tin relativistic calculation which are not present in the muffin-tin calculation. The procedure for constructing the potential in the required form and the modifications to the secular equation are explicitly described.