Bonding of Oxygen on Al(111): A Surface Extended X-Ray Absorption Fine-Structure Study
- 17 December 1979
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 43 (25), 1882-1885
- https://doi.org/10.1103/physrevlett.43.1882
Abstract
The initial ordered chemisorption stage of oxygen on Al(111) has been investigated using polarization-dependent surface extended x-ray absorption fine-structure measurements above the O $K$ absorption edge. The O-Al bond length in the threefold hollow adsorption site has been determined to be 1.79\pm\else\textpm\fi{}0.05 \AA{}. A strong polarization dependence of the extended x-ray absorption fine-structure signal allows the determination of the O-O distance (2.90\pm\else\textpm\fi{}0.05 \AA{}) between the chemisorbed oxygen atoms.
Keywords
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