Two-dimensional liquid polymer diffusion: Experiment and simulation

Abstract
The spreading profiles of small (picoliter) droplets of polydimethylsiloxane on silver surfaces have been monitored in the thickness range below one monolayer. The profile shapes are distinctly non-Gaussian and can be approximated rather well by spherical caps. The experimental shapes and spreading dynamics are compared with Monte Carlo simulations of spreading polymer liquids. Excellent agreement is found.