Structure and Behaviour of Grain Boundaries in Polycrystalline Ice

Abstract

Recent progress in studies of the structure and behaviour of grain boundaries in ice are reviewed. As a lattice geometrical model of the boundary, the coincidence-site lattice (CSL) model is considered for ice crystals. Some evidence of the validity of this model is presented through observations of special shapes of natural snow, results of grain-boundary energy measurements, and direct microscopic observations of boundaries by X-ray diffraction topography. Although methods of measurement of grain-boundary energy have been developed recently, results are still not adequate to be analysed in terms of real energetics for comparison with models of atomic bonding. Modern methods of observing grain boundaries in ice using X-ray diffraction topography are described. Observations of migrating boundaries have revealed that faceting along most closely packed CSL points impede the migration of the CSL boundaries whilst increased numbers of steps among facets with boundaries of other kinds enhance it. The mobility of a fast-moving boundary has been determined to be of the order of 10^-10 cm³ dyn^-1 s^-1 (10^-11 m³ N^-1 s^-1) either in the case when the driving force is the capillary force due to the boundary energy or when it is the stored energy of dislocations.