Radically Polymerizable Pseudorotaxane Monomers: Versatile Building Units for Side Chain Polyrotaxane Synthesis
- 1 February 1999
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 28 (2), 111-112
- https://doi.org/10.1246/cl.1999.111
Abstract
Side chain polyrotaxanes were synthesized from radically polymerizable pseudorotaxane monomers (DB24C8·1) which were composed of secondary ammonium salts having (meth)acryl group at one end and bulky stopper at the other end (1a and 1b) and dibenzo-24-crown-8 (DB24C8). Both radical polymerization of DB24C8·1 and copolymerization of DB24C8·1a with styrene afforded corresponding polymers having rotaxane moieties in the side chains (2a, 2b, and 3).Keywords
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