A theoretical study of the cyano and isocyano groups as α-substituents in alkyl carbanions and carbenium ions
- 1 November 1983
- journal article
- Published by Elsevier in Journal of Molecular Structure: THEOCHEM
- Vol. 105 (1-2), 37-47
- https://doi.org/10.1016/0166-1280(83)80031-1
Abstract
No abstract availableThis publication has 17 references indexed in Scilit:
- Properties of .alpha.-keto cations. Facile generation under solvolytic conditionsJournal of the American Chemical Society, 1982
- Effect of isocyano group substitution in simple primary, secondary, and tertiary carbanionsJournal of the American Chemical Society, 1982
- The stabilities of α-isocyanocarbonium ionsTetrahedron Letters, 1981
- Structures, stabilities, and energies of isomerization of some alkyl cyanides and isocyanides and their corresponding ?-cyanocarbonium and ?-isocyanocarbonium ionsInternational Journal of Quantum Chemistry, 1981
- Possibility of .pi.-electron donation by the electron-withdrawing substituents CN, CHO, CF3, and +NH3Journal of the American Chemical Society, 1980
- Effect of .alpha.-cyano groups on neighboring group participation in carbonium ion reactionsJournal of the American Chemical Society, 1980
- Mesomeric stabilization of carbonium ions by .alpha.-cyano groups. A theoretical evaluation of inductive vs. resonance effects of the cyano moietyJournal of the American Chemical Society, 1980
- The .alpha.-cyano group as a substituent in solvolysis reactions. An evaluation of inductive destabilization vs. mesomeric stabilization of cations by the cyano moietyJournal of the American Chemical Society, 1980
- A nonempirical molecular orbital study on the acidity of the carbon–hydrogen bondThe Journal of Chemical Physics, 1977
- Molecular orbital theory of the electronic structure of molecules. 33. The effect of .alpha.-electropositive substituents on the stabilities of carbenium ionsJournal of the American Chemical Society, 1977