Sphere tensiometry: an evaluation and critique

Abstract
An absolute gravimetric method of measuring surface and interfacial tensions of liquids by pulling a sphere through the interface is examined. The method also permits simultaneous measurement of the contact angle of the liquid on the sphere surface; this enables corrections to be made for incomplete wetting of the solid by liquids in measuring the interfacial tension, a feature which the conventional ring and plate methods lack. Simultaneous measurements of the interfacial tension and the difference in phase densities across the interface are in principle also possible. Preliminary experimental results are presented, and the advantages and disadvantages of the method are critically discussed.