Crystal and Molecular Structure of a Double Complex of Manganese with Phthalocyanato and Pyridine Ligands
- 4 February 1966
- journal article
- research article
- Published by American Association for the Advancement of Science (AAAS) in Science
- Vol. 151 (3710), 569-570
- https://doi.org/10.1126/science.151.3710.569
Abstract
A crystalline solid, formed by oxidation of phthalocyanatomanganese(II) in pyridine, has been identified as phthalocyanatopyridinemanganese(III)-µ-oxo-phthalocyanatopyridinemanganese(III)dipyridinate(C74H42Mn2N18O2C5H5N) byx-ray diffraction methods. This novel molecule consists of two manganese complexes joined by an essentially linear Mn—O—Mn bridge. Its structure may have some relation to oxidation processes in biological systems.This publication has 4 references indexed in Scilit:
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