Palladium-Catalyzed Intramolecular Selenocarbamoylation of Alkynes with Carbamoselenoates: Formation of α-Alkylidene-β-lactam Framework
- 15 June 2005
- journal article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 127 (27), 9706-9707
- https://doi.org/10.1021/ja052175k
Abstract
Pd-catalyzed intramolecular selenocarbamoylation of alkynes leading to alpha-alkylidene-beta-lactams was developed. This reaction can be applied to thiocarbamoylation and to the synthesis of delta- and epsilon-lactams and a cyclobutanone.Keywords
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