STEREOSELECTIVE SYNTHESIS OF 1,2-CIS-GLYCOFURANOSIDES USING GLYCOFURANOSYL FLUORIDES
- 5 June 1983
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 12 (6), 935-938
- https://doi.org/10.1246/cl.1983.935
Abstract
1,2-cis-Ribofuranosides are stereoselectively synthesized in high yields by the reaction of β-ribofuranosyl fluoride and alcohols in the presence of stannous chloride and trityl perchlorate. Under similar condition, α-arabinofuranosyl fluoride reacts with cholestanol to give 1,2-cis-arabinofuranoside predominatly.Keywords
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