Molecular orbital interpretation of the valence X-ray emission of elemental sulphur S8
- 1 November 1972
- journal article
- Published by IOP Publishing in Journal of Physics B: Atomic and Molecular Physics
- Vol. 5 (11), 2032-2038
- https://doi.org/10.1088/0022-3700/5/11/008
Abstract
Semi-empirical extended Huckel and CNDO approximations of the MO-LCAO theory have been used for theoretical interpretation of sulphur K beta X-ray emission from orthorhombic sulphur S8. The results of the calculations are compared with a new high resolution S K beta emission spectrum and with an S LII.III emission spectrum from the literature. The results for K emission are found to be in good agreement with experiment, but the LII.III emission needs still further study.Keywords
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