Grain-boundary diffusion and boundary widths in metals and ceramics

Abstract
A technique is presented to calculate grain‐boundary widths and grain‐boundary diffusion coefficients in metals and nonmetals using grain growth, sintering,diffusion and/or creep data. High‐purity metals yield boundary widths of the order of a few atomic diameters, whereas ionic materials yield ``effective boundary widths'' orders‐of‐magnitude wider.