Existing use of passive microwave radiances to improve temperature and humidity analyses in the troposphere has been largely restricted to ocean applications. Recent studies have shown that useful information can be extracted from the Special Sensor Microwave Imager (SSM/I), particularly for cloud liquid water and precipitation, over many land and ice surfaces. Furthermore, new work has provided improved estimates of emissivity at frequencies well above those normally used for land surface applications using satellite, airborne, and ground-based methods. In the light of these new developments, information theory was used to investigate the potential for microwave atmospheric temperature and humidity sounding over varied land and ice surfaces using the Advanced Microwave Sounding Unit. It was found that significant information is available even at low altitude over land and sea-ice surfaces. With extensive land areas poorly served by conventional in situ sounding methods, this result gives conside... Abstract Existing use of passive microwave radiances to improve temperature and humidity analyses in the troposphere has been largely restricted to ocean applications. Recent studies have shown that useful information can be extracted from the Special Sensor Microwave Imager (SSM/I), particularly for cloud liquid water and precipitation, over many land and ice surfaces. Furthermore, new work has provided improved estimates of emissivity at frequencies well above those normally used for land surface applications using satellite, airborne, and ground-based methods. In the light of these new developments, information theory was used to investigate the potential for microwave atmospheric temperature and humidity sounding over varied land and ice surfaces using the Advanced Microwave Sounding Unit. It was found that significant information is available even at low altitude over land and sea-ice surfaces. With extensive land areas poorly served by conventional in situ sounding methods, this result gives conside...